Dynamic observation of dendrite growth on lithium metal anode …

Validation of the simulation protocols The initial battery geometry of the simulated system (Fig. 1) shows a pseudo-cathode, electrolyte with or without the addition of HF, and a lithium metal ...

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Surface engineering toward stable lithium metal anodes

In 2017, Liang et al. reported that a series of Li-rich composite alloy films (such as Li 13 In 3, LiZn, Li 3 Bi, and Li 3 As) can be synthesized by reacting Li with lithium-based compounds. These alloys can potently prevent the Li dendrite growth, which is attributed to the synergy of fast Li + ion migration through Li-rich ion conductive alloys coupled with an …

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Advanced Thin Film Cathodes for Lithium Ion Batteries

Binder-free thin film cathodes have become a critical basis for advanced high-performance lithium ion batteries for lightweight device applications such as all-solid-state batteries, portable elect... The potential versus specific capacity plot in Figure 1 summarizes the reported up-to-date thin film cathode materials. ...

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Frontiers | Pre-treatments of Lithium Foil Surface for Improving …

This result showed that the SEI film formed on modified Li electrode surface was more conductive and effectively restricted the access of electrolyte to the Li surface. The Li/S battery with a modified Li anode exhibited better cycling performance, since after 100 −1

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Unveiling the Layers: The Anatomy of battery Pouch Films in Lithium …

Battery pouches serve as the protective and flexible enclosures for the vital components within lithium-ion batteries, making them an integral part of the battery construction process. This article delves into the intricate construction of these multi-layered pouch films and explores how each layer contributes to their overall performance and characteristics. The …

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High-performance all-solid-state thin-film lithium microbatteries …

3D electrode design is proposed as an attractive approach to simultaneously increasing energy and power densities for all-solid-state thin film lithium microbatteries (TFBs). However, currently reported TFBs based on 3D electrodes prepared by atomic layer deposition or physical vapor deposition suffer from relatively low areal capacity and high fabrication cost. In …

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Lithium film with abundant stepped structures: A promising route …

Herein, a simple and effective surface activation of lithium anode is performed by a repeated compression process, to enhance the cycling performance of the Li-O 2 batteries. …

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Atomic Layer Deposition for Thin Film Solid-State Battery

Specifically, thin films with high integrity and uniformity are required in the electrolytes of solid-state Li batteries (SSLBs) and the dielectrics of electrostatic capacitors …

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Lithium plating on the anode for lithium-ion batteries during long …

Compared with the above theoretical analysis, post-mortem analysis can demonstrate the battery degradation mechanism more directly. By utilizing X-ray diffraction (XRD) and scanning electron microscope (SEM), Burow et al. [13] found that the distribution of lithium plating and local states of charge is highly inhomogeneous during the low-temperature cycling, …

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Liquid lithium metal processing into ultrathin metal anodes for …

Lithium metal anodes are among the most promising candidates for further increasing the energy density of lithium ion batteries and all-solid-state batteries. A reduction of the anode thickness by using ultrathin lithium metal films is a crucial requirement to achieve a ...

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The aluminum current collector with honeycomb-like surface and …

Durability and safety are main factors contributing to the market requirement of lithium-ion batteries (LIBs) in practical applications. The improvement of current collector has been proven as an effective approach to enhance comprehensive performance of LIBs. To achieve a sufficient electrical contact between the current collector and active materials, …

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Lithium intercalation and structural changes at the LiCoO2 surface ...

1. Introduction Lithium cobalt oxide (LiCoO 2) with a layered rock-salt type structure has been widely used as a lithium intercalation electrode for lithium batteries [1], [2].The LiCoO 2 electrode exhibits stable charge and discharge characteristics with a capacity of 125 mAh g −1 between 3.0 V and 4.2 V (vs. Li/Li +) due to the highly reversible lattice change during …

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Surface Reconditioning of Lithium Metal Electrodes by Laser …

Incorporating lithium metal anodes in next-generation batteries promises enhanced energy densities. However, lithium''s reactivity results in the formation of a native …

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All-Solid-State Thin Film Li-Ion Batteries: New Challenges, New …

All-solid-state batteries (ASSBs) are among the remarkable next-generation energy storage technologies for a broad range of applications, including (implantable) medical devices, portable electronic devices, (hybrid) electric vehicles, and even large-scale grid storage. All-solid-state thin film Li-ion batteries (TFLIBs) with an extended cycle life, broad temperature …

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Surface films of lithium: an overview of electrochemical studies

4. ConclusionsThere is no ambiguity on the existence of surface film on lithium metal when present in a non-aqueous or a solid polymer electrolyte. However, the ambiguity, concerns the role of the surface film in the electrochemical reaction (Li + +e − =Li) that is expected at Li/electrolyte interface. ...

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Advanced Thin Film Cathodes for Lithium Ion Batteries

Binder-free thin film cathodes have become a critical basis for advanced high-performance lithium ion batteries for lightweight device applications such as all-solid-state batteries, portable elect...

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Development of microporous PE films to improve lithium ion batteries ...

Simultaneous polymerization and formation of polyacetylene film on the surface of concentrated soluble ... Y. Polyethylene microporous film for lithium battery separator, Japanese Unexamined Pat ...

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Thin Film Deposition Techniques in Surface …

MS, PLD, CVD, and ALD, as representatives of advanced thin film deposition techniques, together provide the possibility of mass production for surface modification of lithium-ion batteries. Various thin film deposition …

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Multiscale Simulations for Lithium-Ion Batteries: SEI Film Growth …

The solid electrolyte interphase (SEI) film is a key material for lithium-ion battery high cycle performance and safety. In this study, we developed a multiscale model for simulating the 2+1 dimensional SEI film growth in lithium-ion batteries by combining a single ...

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Construction of chromium-free passivation film of pomelo peel …

Construction of chromium-free passivation film of pomelo peel extract on the surface of lithium-ion battery copper foil and study on anti-corrosion mechanism Author links open overlay panel Lei Yang a, Huanlin Zhu b, Shouxing He c, Wei Weng b d, Wen Tan b d, Shuiping Zhong b d e

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Surface-Dependent Performance of Ultrathin TiN Films as an …

An in-depth understanding of lithium (Li) diffusion barriers is a crucial factor for enabling Li-ion-based devices such as three-dimensional (3D) thin-film batteries and synaptic …

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Catalysing surface film formation | Nature Catalysis

The solid electrolyte interphase that forms on graphite anodes plays a vital role in the performance of lithium-ion batteries. Now research shows that the formation of lithium …

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Lithium-film ceramics for solid-state lithionic devices

In this Review, we examine the chemistry and thin-film processing of Li oxides and discuss challenges and opportunities for the integration of Li-oxide films in microbatteries …

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All-solid-state thin-film batteries based on lithium phosphorus ...

Nippon Telegraph & Telephone also developed a series of thin-film batteries fabricated by the RF sputtering method, in which the Li 3 VO 4 –Li 4 SiO 4 solid solution system (Li 3.4 V 0.6 Si 0.4 O 4 and Li 2 O–V 2 O 5 –SiO 2) were employed as the solid 2, WO 3,

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Manufacturing Scale-Up of Anodeless Solid-State …

To maximize the VED, anodeless solid-state lithium thin-film batteries (TFBs) fabricated by using a roll-to-roll process on an ultrathin stainless-steel substrate (10–75 μm in thickness) have been developed. A high-device …

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Surface Reconditioning of Lithium Metal Electrodes by Laser …

Incorporating lithium metal anodes in next-generation batteries promises enhanced energy densities. However, lithium''s reactivity results in the formation of a native surface film, affecting battery performance. Therefore, precisely controlling the chemical and ...

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One-step fabrication of flexible free-standing graphene/sulfur film …

Sulfur dispersion and its electrical conductivity are the key for lithium-sulfur batteries with good cycling stability. In this work, a flexible film composed of reduced graphene oxide (rGO) and sulfur is fabricated from the self-assembly aggregation of sulfur-coated rGO sheets. Not only the three-dimensional rGO network enormously improves the electrical …

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Atomic Layer Deposition for Thin Film Solid-State Battery

The first practical SSLBs were Li-I 2 batteries, which are now utilized in cardiac pacemakers. Their electrolytes are crystalline LiI that forms spontaneously (in-situ) between a cathode [e.g., poly(2-vinylpyridine)] and a Li metal anode. However, the cell voltage of a Li-I 2 battery is approximately 3 V, and the Li + conductivity of LiI is very low, on the order of 10 −7 …

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All-solid-state thin-film batteries based on lithium …

Lithium phosphorus oxygen nitrogen (LiPON) as solid electrolyte discovered by Bates <i>et al</i> in the 1990s is an important part of all-solid-state thin-film battery (ASSTFB) due to its wide electrochemical stability …

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Lithium Batteries and the Solid Electrolyte Interphase …

The formation of the passivation film on graphite was confirmed in 1990 by Fong et al. [] Additionally, Kanamura et al. discovered that the compact layer near the lithium surface was comprised of lithium fluoride (LiF) and lithium oxide (Li 2 …

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Nanostructured thin film electrodes for lithium storage and all-solid ...

Bates et al. [90], [91] first employed Sn 3 N 4 and Zn 3 N 2 as anodes for all-solid-state thin film lithium ion batteries. Neudecker et al. [92] explored the relationship between the composition and performance of SnN x thin film anode in thin-film lithium ion battery.

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High-Voltage Electrolyte Chemistry for Lithium Batteries

High-voltage lithium batteries have some challenges, e.g., electrolyte decomposition, parasitic oxidation reaction, transition metal dissolution and surface cracks and phase changes in regards with c...

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Surface Film Formation on Graphite Negative Electrode in Lithium …

DOI: 10.1149/1.1387981 Corpus ID: 95550968 Surface Film Formation on Graphite Negative Electrode in Lithium-Ion Batteries: AFM Study in an Ethylene Carbonate-Based Solution @article{Jeong2001SurfaceFF, title={Surface Film Formation on Graphite Negative ...

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In situ real-time gravimetric and viscoelastic probing of surface films ...

The solid-electrolyte interphase formed on Li-battery electrodes strongly affects their cycling performance, however the mechanical properties of the surface films are not well-known. Here the ...

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Lithium Batteries and the Solid Electrolyte Interphase …

The formation of the passivation film on graphite was confirmed in 1990 by Fong et al. [] Additionally, Kanamura et al. discovered that the compact layer near the lithium surface was comprised of lithium fluoride (LiF) and lithium oxide (Li 2 O), with the porous

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Preheating Performance by Heating Film for the Safe Application …

The conductivity of the electrolyte and the kinetics of Li+ inside lithium-ion batteries (LIBs) will decrease at low temperatures, which may promote the formation of lithium dendrite. The growing of lithium dendrites will penetrate the separator, and cause the internal short circuits and thermal runaway of cells. Thus, battery preheating is essential to improve the …

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Achieving high performance NASICON film based solid state lithium …

As shown in Fig. 3 d, lithium particles are densely packed on the surface of the lithium, and some LAGP particles adhere to the lithium metal surface due to the high viscosity of the electrolyte. As seen at the top right corner of Fig. 3 d, the surface of the lithium metal turns black due to the decomposition of the electrolyte on the lithium metal surface, forming a thin …

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Role of surface coating on cathode materials for lithium-ion batteries ...

Surface coating of cathode materials has been widely investigated to enhance the life and rate capability of lithium-ion batteries. The surface coating discussed here was divided into three different configurations which are rough coating, core shell structure coating and ultra thin film coating. The mechani

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Ethylene sulfate as film formation additive to improve the ...

Ethylene sulfate (DTD) is investigated as a novel film formation electrolyte additive for graphite anode material in lithium-ion battery. The CV results reveal that DTD is reduced prior to ethylene carbonate (EC) at the interface between graphite and electrolyte, while it cannot prevent the sustained reduction of propylene carbonate (PC) when the amount of DTD …

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