Polymer-assisted crystal growth regulation and defect passivation …

Despite the ongoing breakthroughs in power conversion efficiency (PCE) of perovskite solar cells (PSCs), the presence of inherent defects in perovskite films remains the predominant hurdle impeding the further progress of this promising photovoltaic technology.

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Mechanism of Defect Passivation in Sb2Se3 Solar Cells via Buried ...

This dual passivation mechanism suppresses defect formation and activation, increasing carrier concentration and open-circuit voltage (V OC). Ultimately, employing this …

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Defect passivation strategies in perovskites for an enhanced ...

Since the first introduction of the organic–inorganic hybrid perovskite in the field of optoelectronics, extraordinary progress in both the photoelectric-conversion-efficiency and stability of perovskite solar cells (PSCs) have been witnessed. However, a variety of drawbacks associated with defects in PSCs,

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Mechanism of Defect Passivation in Sb2Se3 Solar Cells via Buried ...

Admittance spectroscopy reveals that Sb 2 Se 3 solar cells with Se seed layers have higher activation energies for defect states and significantly lower defect densities (1.2 × 10 14, 2.7 × 10 14, and 1.3 × 10 15 cm −3 for D1, D2, and D3) compared to an order of magnitude higher densities in Sb 2 Se 3 solar cells without a Se seed layer.

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Defect Passivation of Perovskite Films for Highly Efficient and …

The nonradiative recombination was suppressed more efficiently in the in-film passivation method compared to the posttreatment method due to suppression of the defects not only at the surface but also on the bulk perovskite film, leading to a stabilized PCE of 23.5% for the all-perovskite tandem solar cell.

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Heterojunction lithiation engineering and diffusion-induced defect ...

Heterojunction lithiation engineering and diffusion-induced defect passivation for highly efficient Sb 2 ... (S,Se) 3 solar cells, which is the highest certified efficiency reported for Sb-based solar cells so far. This study provides a convenient method to optimize dual functional layers and heterojunctions for high-performance Sb 2 ...

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Enhancing Performance and Stability of Perovskite Solar Cells …

Enhancing Performance and Stability of Perovskite Solar Cells through Surface Defect Passivation with Organic Bidentate Lewis Bases Weibo Yan, Wensheng Yang, Kangjie Zhang, Hui Yu, Yuntian Yang, Hao Fan, Yuanyuan Qi, ... solar cells was acquired on an Enlitech QE-R3018 using calibrated Si diodes as reference. The electrochemical

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PbS Colloidal Quantum Dots Infrared Solar Cells: Defect …

2. Defects in PbS-QDs Solar Cells 2.1. The Effects of Defects The influence of defects on the solar cell''s performance can be briefed in the low photo-electric current, short carrier lifetime, and deficit in the open circuit voltage. Traps induce inequity of charge carriers at both electrodes and stimulate irradiative recombination.[8]

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Defects and Defect Passivation in Perovskite Solar Cells …

In this review, we provide a systematic introduction to defect passivation in perovskite solar cells, including the effect of defects on devices, and the influence of different types of additives on the PCE of perovskite solar …

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Passivation of defects in perovskite solar cell: From a chemistry …

Since the first report of the solar cell with metal halide perovskite as a sensitizer in 2009 by Miyasaka [8], perovskite solar cells (PSCs) has reached a certificated power conversion efficiency (PCE) of 25.2% in 2019 with an unprecedented rate in the field of photovoltaics [9].During the optimization process of this excellent PCE, many attempts have …

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Bandgap-universal passivation enables stable perovskite solar cells ...

Although metal-halide perovskites are considered "defect-tolerant" (1, 2), they still require careful crystallization and growth (3, 4).Furthermore, defect passivation through molecular bonding or incorporating organic cations that form low-dimensional perovskites that interface to form a passivation "heterojunction" with the three-dimensional (3D) perovskite …

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A theoretical review of passivation technologies in perovskite solar cells

Perovskite solar cells have demonstrated remarkable progress in recent years. However, their widespread commercialization faces challenges arising from defects and environmental vulnerabilities, leading to limitations in energy conversion efficiency and device stability. To overcome these hurdles, passivation technologies have emerged as a promising …

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Defect Passivation Effect of Chemical Groups on Perovskite Solar Cells

Defect passivation is a key strategy to prepare high-performance perovskite solar cells (PVSCs). Even though abundant passivation molecules have been applied, the absence of detailed researches with regard to different functional groups in polymer additives may inevitably impede the establishment of passivation molecules selection rules.

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Multi‐Point Collaborative Passivation of Surface Defects for …

Eliminating these inherent defects is critical for achieving high-efficiency perovskite solar cells. Herein, an organic molecule with multiple active sites (4,7-bromo-5,6 …

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Review Nature of defects and their passivation engineering for ...

This article examines the nature and impact of defects in perovskite solar cells, such as point defects, surface defects, grain boundary defects, and ion migration. It also …

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Substituent engineering in tertiary phosphine oxides for …

Abstract Defect passivation based on Lewis acid–base chemistry has been regarded as an effective strategy to improve the photovoltaic performance and stability of perovskite solar cells (PSCs). ... Substituent engineering in tertiary phosphine oxides for passivating defects of perovskite solar cells. Sun-Ho Lee, Sun-Ho Lee. School of Chemical ...

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Enhanced passivation durability in perovskite solar cells via ...

Defect passivation is regarded as an essential strategy for constructing efficient perovskite solar cells. However, the passivation in long-term operation durability has been largely ignored. Passivator concentration is usually optimized using fresh devices, whereas defect concentration increases with time during actual device operation.

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Defect Passivation through (α-Methylguanido)acetic Acid in …

Defect passivation has become essential in improving efficiency and stability in perovskite solar cells. Here, we report the use of (α-methylguanido)acetic acid, also known as creatine, as a passivation molecule. It is employed both as an additive and as a surface passivation layer of perovskite thin films, given its multiple functional groups, which could …

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Electron injection and defect passivation for high …

Improved electron injection through passivation of defects at the titanium oxide interface has boosted the efficiency of mesoporous perovskite solar cells. In these devices, a layered mesoporous scaffold of carbon, …

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Photocontrolled interfacial defect passivation of coumarin 151 …

Defect passivation has been recognized as an efficient strategy to boost the performance of perovskite solar cells (PSCs) for commercial applications. However, most reported strategies overly emphasize passivation of undesirable defects, while ignoring the inherent instability of perovskite materials caused by environmental risks.

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Perovskite Solar Cells: Passivation Techniques

In terms of perovskite solar cells, passivation materials in perovskite solar cells are materials used to reduce defects and non-radiative recombination losses in the perovskite layer. These materials can either chemically interact with the perovskite to fill trap states or form physical barriers that protect the perovskite surface.

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Passivating perovskite surface defects via bidentate chelation for …

Reducing the trap state density in the perovskite surface is an effective way to enhance the carrier transport dynamics [10] rface passivation of the perovskite active layer can heal inherent defects and suppress interface nonradiative recombination [11].Due to the existence of lone electrons, small Lewis bases molecules containing Sulfur (S) [12], [13], oxygen (O) …

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Passivation strategies for enhancing device performance of …

Download: Download high-res image (194KB) Download: Download full-size image Defect-assisted non-radiative recombination is a leading cause for solar cell performance loss. This review focuses on defect passivation theories and corresponding passivation methods in other solar cell technologies and what we can learn to make perovskite photovoltaic …

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Advanced spectroscopic techniques for characterizing defects in ...

Ranjan, R. et al. Role of PC60BM in defect passivation and improving degradation behaviour in planar perovskite solar cells. Solar Energy Mater. Solar Cells 207, 110335 (2020).

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LiI doping of mixed-cation mixed-halide perovskite solar cells: Defect …

While the reduced hysteresis in the Li0.5 devices can be attributed to defect passivation, the transient response at higher doping levels appears to be correlated to the changing ionic transport properties of the perovskite films. ... Universal approach toward hysteresis-free perovskite solar cell via defect engineering. J. Am. Chem. Soc., 140 ...

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Review Advancements and future directions in defect passivation …

Perovskite solar cells (PSCs) have attracted widespread attention due to their high energy conversion efficiency and low manufacturing cost. Despite their promise, the intrinsic defects in perovskite materials poses substantial challenges. To this end, we conduct an in-depth analysis on the sources and classifications of defects in PSCs, and further clarify the effects of …

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Defects and passivation in perovskite solar cells

This organic-inorganic hybrid perovskite materials have attracted great attention by virtue of their high absorption coefficient, low cost and simple film deposition technique. Based on these advantages, perovskite solar cells have reached an impressive power conversion efficiency over 25%. However, the low-temperature process inevitably leads to a large number …

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Surface passivation of perovskite film for efficient solar …

Planar perovskite solar cells that have been passivated using the organic halide salt phenethylammonium iodide are shown to have suppressed non-radiative recombination and operate with a...

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Surface chemical polishing and passivation minimize non …

Liu, Y. et al. Defect passivation and lithium ion coordination via hole transporting layer modification for high performance inorganic perovskite solar cells. Adv. Mater. 36, 2306982 (2024).

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Defect Passivation Scheme toward High-Performance Halide

Organic-inorganic halide perovskite solar cells (PSCs) have attracted much attention in recent years due to their simple manufacturing process, low cost, and high efficiency. So far, all efficient organic-inorganic halide PSCs are mainly made of polycrystalline perovskite films. There are transmission barriers and high-density defects on the surface, interface, and …

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Enhanced passivation durability in perovskite solar cells via ...

The main bottleneck in the commercialization of perovskite solar cells is the long-term stability of device operation. Sustainable passivation of defects from device operation is an important way to maintain performance over time. We heavily passivate the perovskite surface with a π-conjugated passivator, the passivation effectiveness of which is not concentration …

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Mechanism of Defect Passivation in Sb2Se3 Solar Cells via Buried ...

Admittance spectroscopy reveals that Sb2Se3 solar cells with Se seed layers have higher activation energies for defect states and significantly lower defect densities (1.2 × 1014, 2.7 × 1014, and 1.3 × 1015 cm−3 for D1, D2, and D3) compared to an order of magnitude higher densities in Sb2Se3 solar cells without a Se seed layer.

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Surface Crystallization Enhancement and Defect Passivation for ...

Wide-bandgap (WBG) inverted perovskite solar cells (PSCs) are used as the top cell for tandem solar cells, which is an effective way to outperform the Shockley–Queisser limit. However, the low efficiency and poor phase stability still seriously restrict the application of WBG inverted PSCs. Here, the surface of the WBG perovskite film was passivated by the …

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Understanding the Impact of SAM Fermi Levels on High Efficiency …

1 · Completing the picture of the underlying physics of perovskite solar cell interfaces that incorporate self-assembled molecular layers (SAMs) will accelerate further progress in p-i-n …

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Enhanced passivation durability in perovskite solar cells via ...

solar cells (PSCs), the latest generation of which have outstanding optoelectronic properties, resulting in high PCE values.1–3 Although perovskite materials have comparatively high defect tolerance, defect passivation is still found to be one of the most effective strategies for increasing the PCE of PSCs.4–6 Various passivators

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