Materials and Technologies for Al-ion Batteries

Nonaqueous AIBs. The mature application of nonaqueous organic solvents as electrolytes for Li/Na-ion batteries is not applicable to AIBs considering the high surface charge density of Al 3+.Al 3+ has an ionic radius of 0.0535 nm and carries three positive charges, which means the surface charge density of Al 3+ is 6 times than that of Li + with an ionic radius of …

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Understanding the electrochemical processes of SeS2 positive electrodes ...

Sulfur (S) is considered an appealing positive electrode active material for non-aqueous lithium sulfur batteries because it enables a theoretical specific cell energy of 2600 Wh kg −1 1,2,3. ...

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A Quinone-Based Electrode for High-Performance Rechargeable Aluminum ...

Intensive energy demand urges state-of-the-art rechargeable batteries. Rechargeable aluminum-ion batteries (AIBs) are promising candidates with suitable cathode materials. Owing to high abundance of carbon, hydrogen, and oxygen and rich chemistry of organics (structural diversity and flexibility), small organic molecules are good choices as the …

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High-capacity and small-polarization aluminum …

Zhou et al. demonstrate an organic aluminum battery composed of a quinone-based cathode that shows a reversible Al-storage capacity of 215 mAh g−1, excellent cycling stability, intriguing working voltage …

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Lithiated Prussian blue analogues as positive electrode active ...

Furthermore, we demonstrate that a positive electrode containing Li2-xFeFe(CN)6⋅nH2O (0 ≤ x ≤ 2) active material coupled with a Li metal electrode and a LiPF6-containing organic-based ...

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Rechargeable Iodine Batteries: Fundamentals, …

Lattice distortion and structure collapse are two intrinsic issues of intercalative-type electrodes derived from repeated ion shuttling. In contrast, rechargeable iodine batteries (RIBs) based on the conversion reaction of …

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Recent advances in developing organic positive electrode materials …

The organic positive electrode materials for Al-ion batteries have the following intrinsic merits: (1) organic electrode materials generally exhibit the energy storage chemistry of multi-valent AlCl 2+ or Al 3+, leading to a high energy density together with the light weight of organic materials; (2) the unique coordination reaction mechanism ...

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Naturally abundant high-performance rechargeable aluminum/iodine ...

Rechargeable multivalent ion (Al 3+, Mg 2+ and Zn 2+) batteries provide a viable alternative to lithium ion batteries because of the supply risk of lithium resources and safety concern this study, rechargeable metal–iodine batteries, particularly aluminum/iodine batteries, were fabricated with novel active carbon cloth/polyvinylpyrrolidone (ACC/PVPI) …

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Conjugated sulfonamides as a class of organic lithium-ion positive ...

The first organic positive electrode battery material dates back to more than a half-century ago, when a 3 V lithium (Li)/dichloroisocyanuric acid primary battery was reported by Williams et al. 1.

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A rechargeable iodine-carbon battery that exploits ion ...

The same procedure was used to load iodine into other carbon materials, ... Jung, S.-K. et al. Lithium-free transition metal monoxides for positive electrodes in lithium-ion batteries.

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SnSe nano-particles as advanced positive electrode materials for ...

It is noted that SnSe, as a novel positive electrode material of aluminum-ion battery based on aluminium chloride/1-ethyl-3-methylimidazolium chloride (AlCl 3 /[EMIm]Cl) room temperature ionic liquid electrolyte for the first time, exhibits well-defined discharge voltage plateaus near 1.6 V and a high first cycle specific discharge capacity of ...

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Different positive electrode materials in organic and aqueous …

Therefore, this review is focused on a variety of positive electrode materials, such as transition metal oxides, metal sulfides, carbonaceous materials and other types of materials based on two main electrolyte systems, i.e., the organic system and the aqueous system. In this paper, not only is the working intercalation mechanism ...

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Development of rechargeable high-energy hybrid zinc-iodine …

Here, to circumvent these issues, we use iodine as positive electrode active material in a battery system comprising a Zn metal negative electrode and a concentrated (e.g., 30 molal) ZnCl2 aqueous ...

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Electrolyte design for rechargeable aluminum-ion batteries: …

Phenoxazine polymer-based p-type positive electrode for aluminum-ion batteries with ultra-long cycle life

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Chloroaluminate-Doped Conducting Polymers as Positive Electrodes …

Demonstrated here is the use of conducting polymers as active materials in the positive electrodes of rechargeable aluminum-based batteries operating at room temperature. The battery chemistry is based on chloroaluminate ionic liquid electrolytes, which allow reversible stripping and plating of aluminum metal at the negative electrode. Characterization of …

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Different positive electrode materials in organic and …

Therefore, this review is focused on a variety of positive electrode materials, such as transition metal oxides, metal sulfides, carbonaceous materials and other types of materials based on two main …

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Reversible multielectron transfer I

The calculation of energy density E (Wh l −1) in Fig. 1c was based on the discharge energy and volume of electrolyte on one side (zinc-iodine flow battery 5, bromine-Li 6 (P 2 W 18 O 62) flow ...

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Phenoxazine Polymer‐based p‐type Positive Electrode for Aluminum…

Abstract Aluminum-ion batteries (AIBs) are a promising candidate for large-scale energy storage due to the abundant reserves, low cost, good safety, and high theoretical capacity of Al. ... Phenoxazine Polymer-based p-type Positive Electrode for Aluminum-ion Batteries with Ultra-long Cycle Life. Zhaohui Yang, Zhaohui Yang. School of Materials ...

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Iodine conversion chemistry in aqueous batteries: Challenges ...

After that, rechargeable Li-I 2 [18,19], sodium-iodine (Na-I 2) [20], potassium-iodine (K-I 2) [21], magnesium-iodine(Mg-I 2) [22], and aluminum-iodine (Al-I 2) [23] batteries have been reported, but they all used organic or ionic liquid (IL) electrolyte since the redox potentials of the metal anodes are far below the electrochemical stable ...

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Optimization of Electrolytes for High-Performance …

Metallic zinc (Zn) has been regarded as an ideal anode material for aq. batteries because of its high theor. capacity (820 mA h g-1), low potential (-0.762 V vs. the std. hydrogen electrode), high abundance, low …

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A Review of Anode Materials for Dual-Ion Batteries

Distinct from "rocking-chair" lithium-ion batteries (LIBs), the unique anionic intercalation chemistry on the cathode side of dual-ion batteries (DIBs) endows them with intrinsic advantages of low cost, high voltage, and eco-friendly, which is attracting widespread attention, and is expected to achieve the next generation of large-scale energy storage applications. …

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Hexagonal Composite CuSe@C as a Positive Electrode for High …

As an energy-storage and conversion device, rechargeable aluminum batteries are considered to be a very potential secondary battery system. However, the lack of a suitable positive electrode material with high capacity, good rate capability, and excellent cycling performance hinders the further development of aluminum batteries. In this work, a …

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Layered TiS2 Positive Electrode for Mg Batteries | ACS Energy …

Magnesium batteries are a good candidate for high energy storage systems, but the limited discovery of functional positive electrode materials beyond the seminal Chevrel phase (Mo6S8) has slowed their development. Herein, we report on layered TiS2 as a promising positive electrode intercalation material, providing 115 mAh g–1 stabilized capacity in a Mg …

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Phenoxazine Polymer‐based p‐type Positive …

A p-type poly (vinylbenzyl-N-phenoxazine) (PVBPX) positive electrode is developed for Al-ion batteries (AIBs). The N and O dual active sites in the PVBPX perform a reversible two-step redox reaction with …

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All-carbon positive electrodes for stable aluminium batteries

Wang and coworkers prepared a free-standing Co 9 S 8 @CNT-CNF mat use as binder-free positive electrode materials for aluminium batteries, which exhibit high capacity (315 mAh g −1 at 100 mA g −1), excellent rate performance, and stable cycle life (297 mAh g −1 at100 mA g −1 after 200 cycles).

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Iodine conversion chemistry in aqueous batteries: Challenges ...

In Fig. 1 a, halogens exhibit suitable redox potentials in aqueous batteries; however, in consideration of their physical states (chlorine: gas, bromine: liquid, iodine: solid) at normal pressure and temperature, iodine seems to be the most appropriate. Pure iodine is a bluish-black and lustrous solid. The iodine element ranks the 60th in terms of abundance (0.46 …

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Entropy-increased LiMn2O4-based positive electrodes for fast …

EI-LMO, used as positive electrode active material in non-aqueous lithium metal batteries in coin cell configuration, deliver a specific discharge capacity of 94.7 mAh g −1 at 1.48 A g −1 ...

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A sustainable aqueous Zn-I2 battery | Nano Research

Rechargeable metal-iodine batteries are an emerging attractive electrochemical energy storage technology that combines metallic anodes with halogen cathodes. Such batteries using aqueous electrolytes represent a viable solution for the safety and cost issues associated with organic electrolytes. A hybrid-electrolyte battery architecture has been adopted in a lithium-iodine …

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Robust bilayer solid electrolyte interphase for Zn electrode with …

For the Zn | |I 2 battery, the cut-off voltage was 1.6 V. Anode-free Zn | |Br full cells were assembled by Cu foil as the current collector of negative electrode and Br-based positive electrode ...

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Halogens as Positive Electrode Active Species for Flow Batteries …

The literature on enhancing iodine electrochemical kinetics is lacking compared to that for chlorine and bromine, but generally iodine-based batteries rely on high surface active materials in order to increase the electrode activity towards the (hbox {I}_3^-/{hbox {I}}^-) redox couple. Zhao et al reported a 3.5 V lithium-iodine hybrid flow ...

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