Methods of Fabricating Thin Films for Energy Materials and Devices

The MPM is an emerging liquid phase process capable of fabricating thin films of metal oxides such as TiO 2, LiCoO 2, and p-type Cu 2 O etc. and the functionalities of these thin films in energy devices have been evaluated in a PV-LIB and a dry-type solar cell . Thin films of metallic copper have also been successfully fabricated by the MPM.

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Thin films

The real strength of ALD lies not in the micron-thick films needed for the electrodes in a thin-film battery, but rather in thin films in the range of 0.1nm to 100nm. An electrochemical storage ...

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Thin Film All-solid-state Battery Using Li2MnO3 Epitaxial Film ...

DOI: 10.1246/CL.180773 Corpus ID: 104349419; Thin Film All-solid-state Battery Using Li2MnO3 Epitaxial Film Electrode @article{Hikima2019ThinFA, title={Thin Film All-solid-state Battery Using Li2MnO3 Epitaxial Film Electrode}, author={Kazuhiro Hikima and Kota Suzuki and Sou Taminato and Masaaki Hirayama and Satoshi Yasuno and Ryoji Kanno}, …

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An all-solid-state thin film battery using LISIPON ...

A thin film battery has been fabricated by depositing a LiCoO2 positive electrode, a Li1.9Si0.28P1.0O1.1N1.0 electrolyte, and a Si0.7V0.3 negative electrode, sequentially.

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Fine-Tuning Intrinsic and Doped Hydrogenated Amorphous Silicon Thin ...

In this work, we have prepared both intrinsic and n-type doped hydrogenated amorphous thin silicon films. N-type doped films with variable electrical conductivities were deposited using a mixture of silane (SiH4, 99.999%) and phosphine (2% PH 3 diluted in hydrogen gas, H 2) in which the phosphine flow-rate was intentionally modified.

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Monolithically-stacked thin-film solid-state batteries

Here, the authors predict that stacked thin-film batteries with 0.15-2 µm thin cathodes can achieve a tenfold increase in specific power to over 10 kW kg−1 and demonstrate …

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Solid state thin-film lithium battery systems

Each thin-film battery component, current collectors, cathode, anode, and electrolyte, is deposited from the vapor phase. The final film, a protective coating, is required to prevent the reaction of the lithium from the anode when the battery is exposed to the air. ... Comparative simulation of thin-film and bulk-type all-solid-state batteries ...

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Lithium-film ceramics for solid-state lithionic devices

Thin-film battery materials. ... Garbayo, I. et al. Glass-type polyamorphism in Li-garnet thin film solid state battery conductors. Adv. Energy Mater. 8, 1702265 (2018). Google Scholar

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Atomic Layer Deposition of p‐Type Semiconducting Thin Films: a …

Currently the appropriate p‐type semiconducting compounds are far outnumbered by the n‐type compounds. Hence there is an obvious search for high‐quality thin films of new p‐type compound semiconductors. This is clearly seen in the increasing number of ALD papers published annualy on p‐type semiconducting materials.

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Phenazine-Substituted …

BBL-P films have excellent mechanical properties exemplified by a Young modulus of 11 GPa. The results demonstrate that BBL-P is a promising n-type semiconducting polymer and provide new insights into the effects of backbone structure on electronic structure, thin film microstructure, and charge transport properties of conjugated ladder polymers.

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A mini-review on the development of Si-based thin film anodes for …

For example, the n-type doped 100 nm a-Si thin film and lithium cobalt oxide (LiCoO 2) cathode exhibited only around 60% of the initial reversible capacity at the 30 th cycle (∼1100 mAh g −1) [55]. ... The SS battery cell containing a-Si thin film anode (50–200 nm) with the LiPON electrolyte and a lithiated titanium oxysulfide ...

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Unraveling the Stable Cathode Electrolyte ...

Abstract Spinel-type LiNi0.5Mn1.5O4 (LNMO) is one of the most promising 5 V-class cathode materials for Li-ion batteries that can achieve high energy density and low production costs. ... In this work, a thin-film battery consisting of an LNMO cathode with a solid lithium phosphorus oxynitride (LiPON) electrolyte is tested and their interface ...

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Physical Vapor Deposition in Solid‐State Battery Development: …

The fabrication of thin film battery components, such as thin separator layers and various coatings for different battery designs, is also discussed. ... Cycling properties of thin-film all-solid-state batteries with conversion-type thin-film anode. a) Discharge curve of SiTON, Zn 3 N 4 and Sn 3 N 4 conversion anode in comparison to in-situ ...

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Li–B–O–N electrolytes for all-solid-state thin film batteries

The rocking chair concept with LiCoO 2 /Li–B–O–N/Li multi-layer structure appears to function well in an all-solid-state rechargeable thin film battery. The maximum lithium ionic conductivity of ca. 2.3 × 10 −6 S cm −1 at room temperature was obtained from Li 3.09 BO 2.53 N 0.52 thin film whose activation energy was 0.49 eV.

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All-Solid-State Thin Film Li-Ion Batteries: New

ASSBs are categorized into two types: bulk and thin film types. Compared to bulk-type ASSBs, all-solid-state thin film LIBs (TFLIBs) permit higher charge/discharge rates thanks to the improved contact between the thin film electrodes and SSEs [13]. TFLIBs have been used for many low-power microelectronic devices as onboard energy supply [14,15].

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A flexible thin film lithium battery with a chemical vapor deposited ...

A flexible thin film lithium battery with a chemical vapor deposited organic complex cathode ... Article type Paper. Submitted 22 Dec 2021. Accepted 03 Mar 2022. First published 04 Mar 2022. Download Citation. J. Mater. Chem. A, 2022, 10, 8390-8400 Author version available. Download author version (PDF) ...

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In situ lithiated quinone cathode for ALD/MLD-fabricated high …

We demonstrate that the high-capacity organic electrode material, p-benzoquinone, is able to sustain ultrahigh redox reaction rates without any conductive additives when applied as ultrathin layers in an all-solid-state thin-film battery setup, viable for e.g. high-performance power sources in microelectronic devices. The combined atomic/molecular layer …

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All-solid-state thin-film batteries based on lithium …

The thin-film battery integrates two parts of energy storage and power management and is packaged into a patch-type thin-film battery. The operation voltage of the battery is 3.9 V with the capacity of 100 μ Ah, and …

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Glass-Type Polyamorphism in Li-Garnet Thin Film Solid State Battery ...

a) Schematic representation of a simple planar thin film-based microbattery. b) Arrhenius representation of reported Li 7 La 3 Zr 2 O 12-based thin film in-plane conductivity, [45-56] compared to ...

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Nanocrystalline silicon embedded highly conducting phosphorus …

Hence, n-type silicon thin film comprising highly conducting nanocrystalline islands embed in amorphous silicon matrix is suitable for high power Li-ion battery applications. Discover the world''s ...

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All-solid-state thin-film batteries based on lithium phosphorus …

Lithium phosphorus oxygen nitrogen (LiPON) as solid electrolyte discovered by Bates et al in the 1990s is an important part of all-solid-state thin-film battery (ASSTFB) due to its wide electrochemical stability window and negligible low electronic conductivity. However, the ionic conductivity of LiPON about 2 10 -6 S cm -1</sup> at room temperature is much lower …

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Resistive switching and battery-like characteristics in highly ...

The thinner films show smaller grain size of ~ 15–20 nm and thicker films show a larger grain size ~ 100–150 nm mentioned in Fig. 3b, which seems to be grown larger out of these smaller grains ...

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Introductory Chapter: Lithium-Ion Batteries

Thin film lithium-ion battery. In 2019, the Nobel Prize in Chemistry has been awarded to John B. Goodenough, M. Stanley Whittingham, and Akira Yoshino for their research in improving battery technology. It is the invention of lithium-ion battery (LIB). The energy density of LIB with high discharge voltage (3.6 V) is nearly twice that of Ni-Cd ...

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Nanocrystalline silicon embedded highly conducting phosphorus doped ...

Hence, n-type silicon thin film comprising highly conducting nanocrystalline islands embed in amorphous silicon matrix is suitable for high power Li-ion battery applications. Graphical abstract. ... [22] fabricated thin film a-Si micro battery anodes by low pressure CVD and successfully coupled with LiMn 2 O 4.

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Thin-Film Batteries: Fundamental and Applications

Thin-film batteries are nano- to millimeter-sized solid-state batteries comprising the anode, the cathode, the electrolyte and the separator. The anode is the negative electrode that is oxidized after giving up electrons to …

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Thin

Homepage Products Thin - Film batteries. Next cases. Medical. Industry. Consumer Goods. Resources. Products. Batteries Battery Holders Battery Finder Logistics Packaging. Branches. Industry Medical Consumer Goods. ... Your Reliable Swiss Battery Expert IVM Childsafe Certificate US 1700.20 LinkedIn ...

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Thin-type(CF) | Lithium Battery | Industrial

It is a thin lithium battery that is as thin and light as paper. It contributes to the thinning of devices such as card-type IoT devices. Japanese; Web catalog; Inquiry; Ni-MH Battery; Lithium Battery; Alkaline Battery ... Thin-type(CF) Lithium Primary Batteries. Features. Low self-discharge rate and long life.

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Thin-Film Batteries

Battery Type: Application: 1.5 and 3.0V: Primary Cell: IoT Solutions, Smart Labels, Smart Tags, Wearable Devices: Thin-Film Battery Application Form. ... Additionally, Molex Thin-Film Batteries seamlessly integrate with devices and utilize a stacked construction to reduce internal resistance, enhancing peak current levels and facilitating ...

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Solid state thin-film lithium battery systems

Semantic Scholar extracted view of "Solid state thin-film lithium battery systems" by N. Dudney et al. ... Citation Type. Has PDF. Author. More Filters. More Filters. Filters. Solid-state thin-film rechargeable batteries. N. Dudney. Materials Science, Engineering. 2005; 287. Save. Thin-film solid-state rechargeable lithium battery ...

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Advances in Materials Design for All-Solid-state Batteries: From Bulk ...

All-solid-state batteries (SSBs) are one of the most fascinating next-generation energy storage systems that can provide improved energy density and safety for a wide range of applications from portable electronics to electric vehicles. The development of SSBs was accelerated by the discovery of new materials and the design of nanostructures. In particular, advances in the …

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All-Solid-State Thin Film μ-Batteries for Microelectronics

The all-solid-state battery (ASSB) that uses solid-state electrolyte has become a research trend because of its high safety and increased capacity. The solid-state thin-film μ-battery belongs to the family of ASSB but in a …

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Solid-state thin-film rechargeable batteries

Thin-film solid-state rechargeable lithium batteries are ideal micropower sources for many applications requiring high energy and power densities, good capacity …

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Understanding the effect of p-, n-type dopants and vinyl carbonate ...

In order to understand the doping effect on the cyclability and further improve the developed Si thin films, three types of Si films, undoped, and p-and n-type doped, were sputtered on the prepared substrate and studied as anodes in lithium half-cell using galvanostatic charge-discharge cycling.The structural and morphological characterization was made to …

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Glass‐Type Polyamorphism in Li‐Garnet Thin Film Solid State Battery ...

These findings reveal that glass-type thin film Li-garnet conductors exist for which polyamorphism can be used to tune the Li-conductivity being potential new solid state electrolyte phases to avoid Li-dendrite formation (no grain boundaries) for future microbatteries and large-scale solid state batteries.

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Solid state thin-film lithium battery systems

The Li-free batteries are a special type of a lithium battery recently demonstrated by Neudecker [9] in which the Li anode is formed in situ during the initial charge by electroplating a lithium film at the current collector (e.g. Cu) electrolyte (Lipon) interface. Since the cathode is the only lithium source in such a battery, this is only feasible when the cathode is …

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All-Solid-State Thin-Film Lithium-Sulfur Batteries

The all-solid-state thin-film Li-S battery has been successfully developed by stacking VGs-Li 2 S cathode, lithium-phosphorous-oxynitride (LiPON) solid electrolyte, and Li …

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