Engineering the buried interface in perovskite solar cells via lattice ...

Employing a lattice-matched perovskite oxide as an electron transport layer allows optimizing the buried interface in perovskite solar cells. A maximum power conversion efficiency of 25.17% is ...

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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and ...

Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and Mini-modules Although small-area perovskite solar cells (PSCs) have reached remarkable power conversion efficiencies (PCEs), their scalability still represents one of the major limits toward their industrialization. For the first time, we prove that PSCs fabricated by thermal co-evaporation …

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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells …

Since the advent of the first perovskite solar cells (PSCs) in 2009, 18 their power conversion efficiency (PCE) has reached 25.2%. 19 In addition, the unique band-gap tunability of the perovskite absorber has been explored for engineering semi-transparent PSCs (ST-PSCs) with a suitable optical band gap to complement the absorption of Si solar cells for …

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Advanced Strategies of Passivating Perovskite Defects for High ...

Organic–inorganic halide perovskite (OIHP) solar cells have been developed rapidly due to their superior optoelectronic characteristics, and the power conversion efficiency (PCE) of OIHP solar cells has leapfrogged from 3.9% to 25.2%. [1-6] The attractive photovoltaic performances are highly correlated with the intrinsic nature of OIHP materials: 1) OIHPs are …

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Deep level defect passivation for printable mesoporous CsSnI3 ...

8 · Deep level defects can trap thermally activated electrons or holes, ... Sn 2+ on the surface, resulting in a shallow distribution of states and a decreased density of deep-level …

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Advanced spectroscopic techniques for characterizing defects in ...

Identifying and quantifying defects in perovskite solar cells becomes inevitable to address these challenges and mitigate the deteriorating effects of these defects. This Review …

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Recent Advances in Carbon Nanotube Utilization in …

The power conversion efficiencies of perovskite–silicon tandem solar cells are now 28% under one sun, whereas perovskite–perovskite solar cells are 24.8% efficient . Progress has been made in the device designs and …

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Rotatable Skeleton for the Alleviation of Thermally …

The stability of perovskite solar cells has been identified as the bottleneck for their industrialization. With an aim at tackling this challenge, we self-synthesize a thus-far unreported linearly rotatable structure perovskite, …

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Understanding Defects in Perovskite Solar Cells through …

Point defects may segregate into GBs, IBs, and interfaces, resulting in structural complexity. Defect segregation at GBs and interfaces play crucial roles in carrier transportation …

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Thermally Stable Passivation toward High Efficiency Inverted Perovskite ...

The operational stability of p–i–n perovskite solar cells (PSCs) is dramatically subjected to the quality of the perovskite light harvester and the interface layer atop the perovskite. Herein ...

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Suppressed Defects by Functional Thermally Cross‐Linked …

The affinity of the C═O bond of C-PCBSD with Sn 2+ and Pb 2+ perovskite components has critical benefits for the solar cell performance. The coordination to metal …

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Suppressed Defects by Functional Thermally Cross‐Linked …

Metal halide perovskite solar cells (PSCs) have attracted the photovoltaic community´s attention due to their superior optical and electrical performance, such as tunable bandgap, high carrier transport mobilities, long electron–hole pair diffusion lengths, and small exciton binding energies. As a result, the power conversion efficiency (PCE) of PSCs surged …

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Stability and reliability of perovskite containing solar cells and ...

Stability and reliability of perovskite containing solar cells and modules: degradation mechanisms and mitigation strategies†. Sara Baumann * ab, Giles E. Eperon c, Alessandro Virtuani d, Quentin Jeangros d, Dana B. Kern e, Dounya Barrit f, Jackson Schall eg, Wanyi Nie‡ h, Gernot Oreski i, Mark Khenkin j, Carolin Ulbrich j, Robby Peibst ba, Joshua S. Stein k and …

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Ambient Pressure X-ray Photoelectron Spectroscopy …

Long-term thermal stability is one limiting factor that impedes the commercialization of the perovskite solar cell. Inspired by our prior results from machine learning, we discover that coating a thin layer of 4,4′-dibromotriphenylamine (DBTPA) on top of a CH3NH3PbI3 layer can improve the stability of resultant solar cells. The passivated devices …

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Degradation pathways in perovskite solar cells and how to meet …

In this review, we summarize the main degradation mechanisms of perovskite solar cells and key results for achieving sufficient stability to meet IEC standards. We also …

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Chemical Linkage and Passivation at Buried Interface for Thermally ...

Buried Interface for Thermally Stable Inverted Perovskite Solar Cells with Efficiency over 22% Ying Tan1, Xueqing Chang1, Jun-Xing Zhong1, Wenhuai Feng1, Meifang Yang1, Tian Tian1, Li Gong2 & Wu-Qiang Wu1* 1MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry,SunYat-senUniversity,Guangzhou510006 ...

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Thermally Stable Perovskite Solar Cells by All-Vacuum Deposition

Vacuum deposition is a solvent-free method suitable for growing thin films of metal halide perovskite (MHP) semiconductors. However, most reports of high-efficiency solar cells based on such vacuum-deposited MHP films incorporate solution-processed hole transport layers (HTLs), thereby complicating prospects of industrial upscaling and potentially affecting …

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Thermally Stable Perovskite Solar Cells with Fluoropolymer …

Thermally Stable Perovskite Solar Cells with Fluoropolymer Coating. Yuki Fujita, Yuki Fujita. International Institute for Carbon-Neutral Energy Research "WPI-I 2 CNER", Kyushu University, 744 Motooka, Nishi, Fukuoka, 819-0395 Japan. Department of Applied Chemistry, Kyushu University, 744 Motooka, Nishi, Fukuoka, 819-0395 Japan. Search for more …

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Defects in perovskite-halides and their effects in solar …

This Review describes what is known about the nature and impact of defects in solar cells based on perovskite-halides, with a focus on traps, recombination mechanisms, electrostatics, and...

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Molecular design of defect passivators for thermally stable metal ...

The perovskite solar cell (PSC) community has witnessed unprecedented advancement, with the power conversion efficiency (PCE) of single-junction PSCs soaring from 3.8% in 2009 to 26.0% in 2023. 1 This remarkable progress can be attributed to the superior optoelectronic properties of perovskite, including a high absorption coefficient, 2 long-lived …

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Thermally Stable, Efficient, Vapor Deposited Inorganic Perovskite Solar ...

DOI: 10.1021/ACSAEM.0C00010 Corpus ID: 213999709; Thermally Stable, Efficient, Vapor Deposited Inorganic Perovskite Solar Cells @inproceedings{Gaonkar2020ThermallySE, title={Thermally Stable, Efficient, Vapor Deposited Inorganic Perovskite Solar Cells}, author={Harshavardhan A. Gaonkar and Junhao Zhu and Ranjith Kottokkaran and Behrang …

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Suppressed Defects by Functional Thermally Cross‐Linked …

1 Introduction. Metal halide perovskite solar cells (PSCs) have attracted the photovoltaic community´s attention due to their superior optical and electrical performance, such as tunable bandgap, high carrier transport mobilities, long electron–hole pair diffusion lengths, and small exciton binding energies.

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Favorable grain growth of thermally stable ...

Formamidinium methylammonium lead iodine (FAMAPbI 3) based perovskite solar cells have reached phenomenal efficiencies recently.However, it is difficult to form pure black α-phase perovskite by solution method. Meanwhile, the formed polycrystalline FAMAPbI 3 film often has large amount of grain boundaries, which can consist dangling bonds and iodide …

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Thermal evaporation and hybrid deposition of perovskite solar cells …

Halide perovskite photovoltaics are on the cusp of breaking into the market, but concerns remain regarding the efficiency of large-area devices, operational stability, fabrication speed, and use of toxic solvents. This review discusses various perovskite deposition methods based completely on thermal evaporation and its combination with gas reaction and solution processing to …

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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells …

Perovskite Solar Cells and Mini-modules Jia Li, Hao Wang, Xin Yu Chin, Herlina Arianita Dewi, Kurt Vergeer, Teck Wee Goh, Jia Wei Melvin Lim, Jia Haur Lew, Kian Ping Loh, Cesare Soci, Tze Chien Sum, Henk J. Bolink, Nripan Mathews, Subodh Mhaisalkar, and Annalisa Bruno. Table S1: PSM with active area larger than 10 cm2. Power conversion efficiencies together with the …

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Molecular design of defect passivators for thermally stable metal ...

The perovskite solar cell (PSC) community has witnessed unprecedented advance-ment, with the power conversion efficiency (PCE) of single-junction PSCs soaring from 3.8% in 2009 to 26.0% in 2023.1 This remarkable progress can be attributed to the superior optoelectronic properties of perovskite, including a high absorption

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High-efficiency and thermally stable FACsPbI3 perovskite

α-FA1−xCsxPbI3 is a promising absorbent material for efficient and stable perovskite solar cells (PSCs)1,2. However, the most efficient α-FA1−xCsxPbI3 PSCs require the inclusion of the ...

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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells …

Notably, they achieved a significant milestone by fabricating monolithic, fully textured silicon/perovskite tandem solar cells with a PCE of 24.6% by fully covering the pyramid texture using co ...

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Synergetic surface charge transfer doping and passivation toward …

Organic-inorganic lead halide perovskite solar cells (PSCs) have received much attention in the last few years due to the high power conversion efficiency (PCE). Generally, perovskite/charge transport layer interface and the defects at the surface and grain boundaries of perovskite film are important factors for the efficiency and stability of PSCs. Herein, we …

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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells …

Article Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and Mini-modules Jia Li,1 Hao Wang,1 Xin Yu Chin,1 Herlina Arianita Dewi,1 Kurt Vergeer,1 Teck Wee Goh,2 Jia Wei Melvin Lim,1,2 Jia Haur Lew,1 Kian Ping Loh,3 Cesare Soci,2 Tze Chien Sum,2 Henk J. Bolink,4 Nripan Mathews,1,5,* Subodh Mhaisalkar,1,5,* and Annalisa Bruno1,6,* SUMMARY The rapid …

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Fully low-temperature processed carbon-based perovskite solar cells ...

Semantic Scholar extracted view of "Fully low-temperature processed carbon-based perovskite solar cells using thermally evaporated cadmium sulfide as efficient electron transport layer" by Zhiyong Liu et al. Skip to search form Skip to main content Skip to account menu. Semantic Scholar''s Logo. Search 221,834,863 papers from all fields of science. Search. …

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Efficient Thermally Evaporated γ‐CsPbI3 Perovskite …

1 Introduction. Organic–inorganic hybrid perovskites have aroused increasing attention due to their excellent photophysical properties. [1, 2] The power conversion efficiency (PCE) of perovskite solar cells (PSCs) has …

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Enhanced passivation durability in perovskite solar cells via ...

The main bottleneck in the commercialization of perovskite solar cells is the long-term stability of device operation. Sustainable passivation of defects from device operation is an important way to maintain performance over time. We heavily passivate the perovskite surface with a π-conjugated passivator, the passivation effectiveness of which is not …

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Advanced spectroscopic techniques for characterizing defects in ...

The development and study of perovskite solar cells is a contemporary area due to their favorable characteristics such as tunable bandgap, high absorption coefficient, low exciton binding energy ...

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A Facile Surface Passivation Enables Thermally Stable and …

Although perovskite solar cells (PSCs) have attracted enormous attention owing to their fascinating optoelectronic properties and solution processability, defects in PSCs, which adversely affect efficiency and stability, are still not completely resolved. Herein, a novel indacenodithieno[3,2‐b]thiophene‐based small molecule (SM) additive (IDTT‐ThCz), capable of …

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Trimming defective perovskite layer surfaces for high-performance solar ...

The modified perovskite thin film, with a 50 nm top layer removed, exhibited a reduced bandgap, enhanced carrier lifetime, and decreased strain and defect concentration. Perovskite solar cells derived from this refined top surface deliver a champion power conversion efficiency of 26.25% (certified efficiency of 25.5%).

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Understanding the thermal degradation mechanism of perovskite …

The magnitude of normalized 1/f noise (shown in figure 5(d)) in degraded perovskite solar cell is four orders of magnitude higher than the pristine device, which proves …

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Molecular design of defect passivators for thermally …

The perovskite solar cell (PSC) community has witnessed unprecedented advancement, with the power conversion efficiency (PCE) of single-junction PSCs soaring from 3.8% in 2009 to 26.0% in 2023. 1 This …

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Review Nature of defects and their passivation engineering for ...

Point defects, such as Schottky and Frenkel defects, can contribute to the formation of trap states in perovskite solar cells (PSCs). These defects introduce localized …

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Universal defects elimination for high performance thermally …

Inorganic CsPbBr3 perovskite has emerged as a promising material for fabricating highly stable perovskite solar cell devices. However, during the formation of thermally evaporated CsPbBr3 film, an ...

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