Materials of Tin-Based Negative Electrode of Lithium-Ion Battery …

Abstract Among high-capacity materials for the negative electrode of a lithium-ion battery, Sn stands out due to a high theoretical specific capacity of 994 mA h/g and the presence of a low-potential discharge plateau. However, a significant increase in volume during the intercalation of lithium into tin leads to degradation and a serious decrease in capacity. An …

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A Commercial Conducting Polymer as Both Binder and

Unlabelled: This work describes silicon nanoparticle-based lithium-ion battery negative electrodes where multiple nonactive electrode additives (usually carbon black and an inert polymer binder ...

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Single-Nanometer-Sized Boron and Phosphorus Co-Doped Silicon ...

DOI: 10.1021/acsanm.3c04824 Corpus ID: 266262815; Single-Nanometer-Sized Boron and Phosphorus Co-Doped Silicon Nanoparticles for Negative Electrode of Lithium-Ion Batteries

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Nano-silicon composite negative electrode material used for …

The nano-silicon composite negative electrode material of the present invention has features of high specific capacity (higher than 1000 mAh/g), high initial charge-discharge efficiency (higher than 93%) and high conductivity. ... Preparation method of lithium ion battery negative electrode material CN106129411B (en) * 2016-09-19: 2020-01-24: ...

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Poly(phenanthrenequinone) as a conductive binder for nano-sized silicon …

- "Poly(phenanthrenequinone) as a conductive binder for nano-sized silicon negative electrodes" Fig. 3. (a); The transient voltage profiles obtained from galvanostatic intermittent titration technique and (b); the evolution of internal resistance derived from the difference between the end of closed-circuit-voltage (CCV) and the quasi-open ...

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A Commercial Conducting Polymer as Both Binder and …

This work describes silicon nanoparticle-based lithium-ion battery negative electrodes where multiple nonactive electrode additives (usually carbon black and an inert polymer binder) are replaced with a single conductive …

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Innovative Solutions for High-Performance Silicon Anodes in …

Silicon (Si) has emerged as a potent anode material for lithium-ion batteries (LIBs), but faces challenges like low electrical conductivity and significant volume changes during lithiation/delithiation, leading to material pulverization and capacity degradation. Recent research on nanostructured Si aims to mitigate volume expansion and enhance electrochemical …

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Constructing novel Si@Sn-SnO2@C dual core-shell composite …

As shown in Fig. 6 a, utilizing the better cycling performance and rate capability of Si@Sn-SnO 2 @C as the negative electrode, a full battery system is created using Li 1.2 Ni …

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How carbon coating or continuous carbon pitch matrix influence …

1 INTRODUCTION. Silicon is known as one of the best negative electrode candidates for Li-ion batteries (LIBs) applications. Its alloying with lithium may theoretically lead to specific capacities in LIB as high as 3580 mA h g −1 with the formation of Li 15 Si 4, the most lithiated phase electrochemically formed at room temperature.The relatively low potential (0.4 V vs. Li + /Li) of …

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Pitch-based carbon/nano-silicon composite, an …

Pitch-based carbon/nano-silicon composites are proposed as a high performance and realistic electrode material of Li-ion battery anodes. Composites are prepared in a simple way by the pyrolysis under argon …

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Silicon-Carbon composite anodes from industrial battery grade silicon …

This work clearly demonstrates the potential of industrial battery grade silicon from Elkem. ... Mihashi, M., Yamagata, M. & Ishikawa, M. Electrochemical properties of non-nano-silicon negative ...

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Si nanomaterials in lithium-ion battery anode

Silicon is a promising material for negative electrode in Li-ion batteries because of high gravimetric capacity. A Si nanomaterial that can accommodate volume expansion accompanied by lithiation ...

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Poly(phenanthrenequinone) as a conductive binder for nano-sized silicon …

Current density = 100 mA gSi −1 (0.028 C). - "Poly(phenanthrenequinone) as a conductive binder for nano-sized silicon negative electrodes" ... Silicon nanoparticle-based lithium-ion battery negative electrodes where multiple nonactive electrode additives are replaced with a single conductive binder, in this case, the conducting polymer PEDOT ...

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Conductive Polymer Binder for High-Tap-Density Nanosilicon …

High-tap-density silicon nanomaterials are highly desirable as anodes for lithium ion batteries, due to their small surface area and minimum first-cycle loss. However, this material poses formidable challenges to polymeric binder design. Binders adhere on to the small surface area to sustain the drastic volume changes during cycling; also the low porosities and …

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Bulk-Nanoporous-Silicon Negative Electrode with Extremely …

We synthesized freestanding bulk three-dimensional nanoporous Si using dealloying in a metallic melt, a top-down process. Using this nanoporous Si, we fabricated negative electrodes with high lithium capacity, nearing their theoretical limits, and greatly extended cycle lifetimes, considerably improving the battery performance compared with those …

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Electrochemical Synthesis of Multidimensional Nanostructured Silicon …

Silicon (Si) is a promising negative electrode material for lithium-ion batteries (LIBs), but the poor cycling stability hinders their practical application. ... Electrochemical Synthesis of Multidimensional Nanostructured Silicon as a Negative Electrode Material for Lithium-Ion Battery ACS Nano. 2022 May 24;16(5):7689-7700. doi: 10.1021 ...

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Advanced silicon-based electrodes for high-energy lithium-ion …

Hierarchical micro/nano porous silicon Li-ion battery anodes. Chem. Commun., 48 (2012), pp. 5079-5081. Crossref View in Scopus Google Scholar [53] ... Spray drying method for large-scale and high-performance silicon negative electrodes in Li-ion batteries. Nano Lett., 13 (2013), pp. 2092-2097. Crossref View in Scopus Google Scholar [65]

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Si particle size blends to improve cycling performance as negative ...

Silicon negative electrodes dramatically increase the energy density of lithium-ion batteries (LIBs), but there are still many challenges in their practical application due to the limited cycle …

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Electrochemical properties of non-nano-silicon negative electrodes ...

Fig. 2 (a) and (b) show the charge and discharge curves of the cell including PI-Si and the SBR-Si electrodes. The initial charge capacities of the PI-Si and SBR-Si electrodes at low current density (200 mA g −1) are ca. 2760 and 2870 mAh g −1; there is no significant difference between these values.On the other hand, the initial discharge capacities of the PI-Si and SBR …

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Nanoscale Chemical Evolution of Silicon Negative Electrodes ...

This study emphasizes how initial heterogeneities in the percolating electronic network and the porosity affect SiNPs aggregates along cycling and pinpoint the crucial role of an optimized formulation in silicon-based thick electrodes. Continuous solid electrolyte interface (SEI) formation remains the limiting factor of the lifetime of silicon nanoparticles (SiNPs) based …

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Imaging of 3D morphological evolution of nanoporous silicon …

Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model. Radvanyi, Etienne; Porcher, Willy; De Vito, Eric; ... 3D morphological evolution of Li-ion battery negative electrode LiVO2 during oxidation using X-ray nano-tomography. Chen-Wiegart, Yu-chen Karen; Shearing, Paul; Yuan, Qingxi;

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Regulated Breathing Effect of Silicon Negative Electrode for ...

Si is an attractive negative electrode material for lithium ion batteries due to its high specific capacity (≈3600 mAh g–1). However, the huge volume swelling and shrinking during cycling, which mimics a breathing effect at the material/electrode/cell level, leads to several coupled issues including fracture of Si particles, unstable solid electrolyte interphase, and low …

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A solid-state lithium-ion battery with micron-sized silicon anode ...

Structure manipulation such as nano-crystallization can enhance the cycle stability of the Si electrode 13,34,35. However, the sophisticated structural design greatly raises the cost.

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Nanosilicon-based negative electrodes for lithium-ion batteries

A technique for manufacturing negative electrodes with silicon nanofibers for lithium-ion batteries has been developed. The electrochemical behavior of such electrodes at lithium insertion ...

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Carbon−Silicon Core−Shell Nanowires as High …

We introduce a novel design of carbon−silicon core−shell nanowires for high power and long life lithium battery electrodes. Amorphous silicon was coated onto carbon nanofibers to form a core−shell structure and …

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Preparation and electrochemical performances for silicon-carbon …

In recent years, with the continuous development of technologies such as electric vehicles, military equipment, and large-scale energy storage, there is an urgent need to obtain new lithium-ion battery electrode materials with high electrochemical performances [1,2,3].The negative electrode as an important component of lithium-ion batteries seriously effects the …

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Silicon micropowder negative electrode endures more than 1000 …

Semantic Scholar extracted view of "Silicon micropowder negative electrode endures more than 1000 cycles when a surface-roughened clad current collector is used" by R. Kataoka et al. ... a good anode for Li-ion battery applications must exhibit dimensional stability upon Li insertion, as well as chemical inertness with respect to the ...

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Nano-Silicon composite materials with N-doped graphene of …

The initial discharge capacity of Nano-Si@NG electrode (based on the weight of Nano-Si@NG) is 1712.2 mA h g −1. It showed a good initial coulombic efficiency of 71.5%. The large capacity loss of Nano-Si@NG electrode can be ascribed to the irreversible formation of SEI film and partial lithium-ion absorbed by NG [31]. The coulombic efficiency ...

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Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode …

We introduce a novel design of carbon−silicon core−shell nanowires for high power and long life lithium battery electrodes. Amorphous silicon was coated onto carbon nanofibers to form a core−shell structure and the resulted core−shell nanowires showed great performance as anode material. Since carbon has a much smaller capacity compared to …

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Research progress on nano silicon-carbon anode materials for

Research progress on nano silicon-carbon anode materials for lithium ion battery ZHOU Junhua 1, LUO Fei ... reported the important role of nanotechnology in improving the performance of silicon negative electrode, it has continued to explore many basic scientific issues and industrial applications of nano silicon-based materials by mainly ...

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Supremely elastic gel polymer electrolyte enables a …

Silicon-based materials are promising anodes for next-generation lithium-ion batteries, owing to their high specific capacities. However, the huge volume expansion and shrinkage during cycling ...

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Mesoporous silicon sponge as an anti-pulverization structure for …

Three-dimensionally engineered porous silicon electrodes for Li ion batteries. ... Three-dimensional metal scaffold supported bicontinuous silicon battery anodes. Nano Lett. 12, 2778–2783 (2012).

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Lithium ion battery silicon carbon composite negative electrode ...

Si sill is a kind of conventional lithium ion battery negative material, that in the material that people study up to now, theoretical specific capacity is the highest, the theoretical specific capacity of pure silicon is 4200mAh/g, much larger than the negative material native graphite of present stage commercialization and the theoretical capacity of Delanium, and silicon alloy has solvation ...

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